The hottest celeb couple who stole the spotlight at this Oscars Sunday was none other than the most celebrated star couple, Brangelina.

The Descendants star George Clooney and his new girlfriend Stacy Keibler also complemented each other quite well.

Brad Pitt and Angelina Jolie walked the red carpet wearing matching black outfits. While Jolie showed-off some skin in high slit jet black Versace gown, her beau kept it poised and stylish.

The best actor nominee, George Clooney, showed-off the gorgeous new women in his life. The couple grabbed all the limelight as they arrived at the red carpet at Kodak Theater, Calif, Sunday.

Other celebrity couples who charmed the audience include Natalie Portman and fiancé Benjamin Millepied, Melanie Griffith and Antonio Banderas and several others.

Check out the photographs here. Who looks the best?

Brad Pitt and Angelina Jolie arrive at the 84th Academy Awards.
Brad Pitt and Angelina Jolie arrive at the 84th Academy Awards. www.oscar.go.com
George Clooney and Stacy Keibler arrive at the 84th Academy Awards.
Although George Clooney may be dating Stacy Keibler, that hasn't stopped rumors about his sexuality. www.oscar.go.com
Benjamin Millepied and Natalie Portman
Benjamin Millepied and Natalie Portman are reportedly married, and Portman's apparent wedding band can be seen in this image of the pair arriving at the 84th-annual Academy Awards. www.oscar.go.com
Colin Firth and Livia Giuggioli arrive at the 84th Academy Awards.
Colin Firth and Livia Giuggioli arrive at the 84th Academy Awards. www.oscar.go.com
Judd Apatow and Leslie Mann arrive at the 84th Academy Awards.
Judd Apatow and Leslie Mann arrive at the 84th Academy Awards. www.oscar.go.com
Nominee Gary Oldman and Alexandra Edenborough arrive at the 84th Academy Awards.
Nominee Gary Oldman and Alexandra Edenborough arrive at the 84th Academy Awards. www.oscar.go.com
Nominee Jean Dujardin and Alexandra Lamy arrive at the 84th Academy Awards.
Nominee Jean Dujardin and Alexandra Lamy arrive at the 84th Academy Awards. www.oscar.go.com
Melanie Griffith and Antonio Banderas arrive at the 84th Academy Awards.
Melanie Griffith and Antonio Banderas arrive at the 84th Academy Awards. www.oscar.go.com
Chris Pratt and Anna Faris arrive at the 84th Academy Awards.
Chris Pratt and Anna Faris arrive at the 84th Academy Awards. www.oscar.go.com
Berenice Bejo and Michel Hazanavicius arrive at the 84th Academy Awards.
Berenice Bejo and Michel Hazanavicius arrive at the 84th Academy Awards. www.oscar.go.com
Viola Davis and Julius Tennon arrive at the 84th Academy Awards.
Viola Davis and Julius Tennon arrive at the 84th Academy Awards. www.oscar.go.com
Brad Pitt Brad Pitt