The 2012 Golden Globes brought attracted all of Hollywood's A-list stars, but some had more eyes on them than others. Brad and Angelina, Jessica Biel and Giuliana Rancic were all major centers of attention Sunday night.

Brad and Angelina Share Their Love

Brad and Angelina were certainly a main attraction of the night. The stunning couple glided onto the red carpet after exiting a black limousine. Twitter was abuzz with fans swooning over Pitt opening the car door for Jolie. Brad Pitt never allows anyone else to open a door for Angelina Jolie. He will ALWAYS wave off the attendant. Hot, right? tweeted @LaineyGossip.

Jolie looked ravishing in a white and red Atelier Versace silken gown with matching red clutch and lipstick. Pitt look just as handsome in a three-piece Salvatore Ferragamo tuxedo. You're prettier than me, Jolie gushed to her beau as they arrived at the CAA after-party at Sunset Tower.

Though the couple left empty-handed -- Jolie's In the Land of Blood and Honey lost in the Best Foreign Language Film category and Pitt's Moneyball  lost Best Actor, Drama to George Clooney - they had other things to be happy about.

Jolie told The Associated Press that what she was most looking forward to that evening was Getting into bed with Brad! she said with a wink.

Jessica Biel Wear Wedding White

Although she reportedly just got engaged to superstar Justin Timberlake, Jessica Biel attended the Golden Globe Awards solo Sunday night. The brunette actress - who revealed a darker hair color at the event - wore a beautiful white lace Elie Saab dress.

She accessorized with sparklers on her fingers, wrists and neck. A Tiffany & Co. $25,000 platinum and yellow gold diamond ring and a set of five diamond band rings worth $9,500 graced her fingers, according to The NY Daily News. She also added $243,000 diamond stud earrings and a $135,000 opera length necklace.

One noticeably absent jewel was a wedding band. The 29-year-old reportedly accepted a proposal from boyfriend Timberlake while the couple vacationed in Montreal over the holidays. However, no engagement ring could be seen on her finger Sunday night. Many were left puzzled.

Timberlake's grandmother, however, has confirmed the engagement. Yes, Justin is engaged, Sadie Bomar told earlier this month. Jessica is a very sweet girl, she's upright and everything and we love her. She's a wonderful campaigner for the environment and Justin is too, a fine young man. Jessica will be a lovely member of the family.

Giuliana Rancic, Healthy and Back to Work

Since announcing that she had breast cancer last month, E! host Giuliana Rancic has been outspoken about her struggle. But on Sunday night, the TV personality was all smiles. Rancic hit the red carpet to do what she does best. She wowed in a floor-length gray and black Monique Collignon gown. Well-wishers took to Twitter to dish on how gorgeous Rancic look, after a difficult double mastectomy. Guiliana Rancic rocked 2 looks on the Golden Globes red carpet. back like she never left! tweeted @GlobalGrind. Giuliana Rancic is looking super glam in floor-length gown! tweed @CELEBUZZ.

The 36-year-old recently opened up to Michigan Avenue magazine about her fight against cancer. People come up and they have sadness in their eyes, and I think, at a time when everyone's looking at me with pity, I look at myself as lucky, she told the Chicago-based publication. I think I just dodged the biggest bullet of my life. 

I think because breast cancer touches so many people, when someone hears you have it, they just shower you with love, she said. The one word I always saw in all the messages was strong. You're so strong, stay strong, be strong -- when you hear something enough, you start believing it.

I don't give two sh**s about my breasts. I didn't care that at the Golden Globes, I wouldn't be able to show cleavage, Rancic said, adding that many were surprised by her choice to have the surgery. They said, 'Are you sure you want to do this? Think about the life you lead and the fabulous dresses and that's part of your job. It could put your job in jeopardy.' And I thought, if I ever have a job that is defined by my breasts and some gorgeous gown then I'm in the wrong business.

Elle Macpherson Loved Presenting with Ashton Kutcher 

Elle Macpherson was nervous about presenting at Sunday night's Golden Globes. But she said that her favorite moment was presenting with Ashton [Kutcher]. The 47-year-old supermodel and upcoming host of NBC's Fashion Show had nothing but kind words for Kutcher, calling him fantastic and supportive. 

I was very nervous because this is the first time I've been to the Golden Globes, she told Us Weekly. It was a huge honor for me for the Hollywood Foreign Press to ask me to come and represent Fashion Star. 

She also thought his physical stature did not hurt. I think probably because we are the same height! He was the only person I could present with, the 6-foot supermodel said.

The blonde stunner turned heads in a blush hued Zac Posen dressed. Even though her body looked fit to a T, she insisted that she has not been strict with her diet. Actually, I had chicken fingers and fries at lunch! I was so hungry I swear to goodness! she joked. You can call the Peninsula hotel and check my room service bill! Macpherson said in a red carpet interview that drinking lots of water helps keep her body in check.