[11:45] British director Guy Ritchie (R) and his girlfriend British actress Jacqui Ainsley
British director Guy Ritchie and now-wife Jacqui Ainsley pose at the premiere of "Sherlock Holmes: A Game of Shadows" at the Empire Cinema in London Dec. 8, 2011. Reuters/Suzanne Plunkett

Newlyweds Guy Ritchie and Jacqui Ainsley made their first post-wedding appearance at the world premiere of the 46-year-old director’s new movie “The Man From U.N.C.L.E” during the Film4 Summer Screen at Somerset House in London. The 33-year-old looked beautiful in a Temperley London sheer overlay white-caped gown. Ritchie matched his ladylove in white pants and a blue suit jacket.

The couple looked a picture of marital bliss on the red carpet and Ainsley even stuck to a white bridal floor-length gown. Ritchie looked dapper in tailored pants, pale blue shirt, skinny navy tie and matching jacket, US Weekly reported.

The gorgeous white tulle and chiffon dress featured intricate gold detailing and is by one of Ainsley's favorite designers, Alice Temperley. As part of her Temperley London collection, this gown is available to buy at Luisa via Roma.

Ainsley showed off her svelte frame in the billowing gown. Her brown hair was swept off her face and styled in a pulled back updo. Ainsley turned heads in the striking ensemble.

She matched her look with chunky white ankle-strap sandals. Her accessories included a pair of long earrings, a bracelet and her new gold wedding band. The mother of three also carried a metallic box clutch to finish her look. Her makeup consisted of lots of bronzer and brown lipstick.

They even packed on the PDA at the event. The couple managed to have some fun on the red carpet with the model hopping on a vintage Vespa while her husband watched.They were joined at Somerset House for the special Film 4 screening of the movie by Henry Cavill, who features as the lead in the action flick and was a guest at the nuptials last weekend. Ritchie will now be in full promotional mode for his latest film, a reboot of the classic '70s TV series.

The pair tied the knot before pals including Brad Pitt, David Beckham, Jason Statham, and Rosie Huntington-Whiteley, among others, at their sprawling Wiltshire estate, Ashcombe House, July 30. Ainsley looked stunning at her wedding, glowing in a white lace gown with a flower crown atop her hair.