The 2012 MTV Movie Awards red carpet was extra-chic on Sunday night, with stars like Charlize Theron, Kristen Stewart and Jennifer Aniston opting for sophisticated, rather than outrageous, looks.

I think you have to try and not be trendy and just be comfortable. I'm really fortunate to work with really talented people in the industry, Charlize Theron told MTV's Kat Graham, about her look. At the end of the day, I have to put it on and feel like me. Theron, who stars as the wicked witch in Snow White and the Huntsman, wore a red Lanvin peplum dress with gold Jimmy Choo sandals and Cartier jewelry.

Theron's co-star in the film, Kristen Stewart, looked equally as glamorous on the MTV Movie Awards red carpet in a black, silver and lime Guishem dress with Christian Louboutin heels and a Repossi ring. Stewart wore her hair in wild tousles paired with smoky eyes for the red carpet. The 22-year-old actress won the award for Best Kiss shared with boyfriend Robert Pattinson in The Twilight Saga: Breaking Dawn -- Part 1.

Speaking of hot Hollywood couples, Jenna Dewan and husband Channing Tatum walked the red carpet arm-in-arm. The 31-year-old actress was by far one of the best dressed of the night in a Lublu dress, featuring a mint-green, low-cut silk top and a white-tiered skirt. She also donned Sergio Rossi shoes and Norm Silverman jewelry. Heading to MTV awards! Let's hope @channingtatum comes home with a few! Jenna tweeted on her way to the MTV Movie Awards. Unfortunately, Tatum, who was nominated in three categories, did not bring home any golden popcorn.

A style and award winner of the night was Jennifer Aniston, who took home a golden popcorn trophy for Best On-Screen Dirtbag for her role in Horrible Bosses. Aniston looked super sexy in a black leather, one-shoulder Valentino dress with Giuseppe Zanotti heels. She had her famous hair pin-straight and skin bronzed.

Some scored major points with on-trend styles, such as Elizabeth Banks and Nikki Reed. Banks went with a black Elie Saab jumpsuit with laced web detailing from the designer's fall 2012 collection. She added hot-pink nails and pointed pumps to her look. Reed matched a glistening gold Randi Rahm 1940s dress with a Pierre Hardy leopard-print clutch with gold geometric cubes for a fierce combination. 

Check out other best-dressed stars from the 2012 MTV Movie Awards.