Rihanna headed to the Victori's Secret Fashion show wearing thigh-high boots, showing the models that they are not the only sexy women.

(View photos here.)

The Barbadian beauty is set to perform at the annual fashion show, as is Justin Bieber.

Along with the thigh-high black boots, Rihanna also wore a ‘Trackstar’ sweatshirt and an army fatigue coat.

The singer arrived in New York on Tuesday, after revealing that Chris Brown would be making a feature on her seventh album, ‘Unapologetic,’ set to debut on Nov. 19.

The song title is "Nobodies Business" and sounds like it will be about their on-and-off again relationship.

Earlier this year, three years after Rihanna and Brown broke up due his domestic assault, the pair caused controversy when she featured him on the remix of her song, "Birthday Cake." On the track, Brown sings, "Girl I wanna [expletive] you right now. Been a long time. I’ve been missing your body. Let me turn the lights down. When the window go down, it's a private party."

Rihanna also sang on his song, ‘Turn Up the Music,’ saying, “"Turn up themusic cause I feel a little turned on/ Turn on the music, don't you try to turn me down." She later says, “I love you baby.”

But not everyone is excited about Rihanna working with Chris Brown again or involving herself with him romantically.

Rihanna has made no secret about her love for Brown, though he gave her a black eye and a swollen lip after a heated argument just three years ago.

"My stomach drops and I have to maintain this poker face and not let it get to the outer part of me,”Rihanna explained to Oprah earlier this year about how she acts when she sees Brown.

"We love each other and we probably always will."

This past weekend, Rihanna tweeted, "Man my album is complete, and I need a [expletive] drink and a roll up! It was quite the journey, but it's all part of our story!”