The hottest celeb couple who stole the spotlight at this Oscars Sunday was none other than the most celebrated star couple, Brangelina.

The Descendants star George Clooney and his new girlfriend Stacy Keibler also complemented each other quite well.

Brad Pitt and Angelina Jolie walked the red carpet wearing matching black outfits. While Jolie showed-off some skin in high slit jet black Versace gown, her beau kept it poised and stylish.

The best actor nominee, George Clooney, showed-off the gorgeous new women in his life. The couple grabbed all the limelight as they arrived at the red carpet at Kodak Theater, Calif, Sunday.

Other celebrity couples who charmed the audience include Natalie Portman and fiancé Benjamin Millepied, Melanie Griffith and Antonio Banderas and several others.

Check out the photographs here. Who looks the best?