One of Tiger Woods’ former mistresses, an ex-porn star named Devon ‘XXX’ James, has some cautionary words for his new girlfriend, Olympic alpine-skiier Lindsey Vonn.

According to the NY Post, James, who is better known as the 16th woman to come forward in the Tiger Woods sex scandal in 2009, was shocked by the news that Woods and Vonn are dating because she doesn’t believe that the skier is Woods’ type. James also suggested that Woods might already be cheating on Vonn.

“You know when the pics came out of Tiger and his new girlfriend — somewhere, 15 other girls were going, ‘Huh? I thought I was his girlfriend!’ ” James said on Tuesday.

“I thought he would have picked a woman who was more petite and not someone who is more muscular and has a bigger head than his,” she told TMZ. “Maybe his taste has changed since [ex-wife Elin Nordegren] and the 27 mistresses.”

But that seemed to be exactly the message Woods was sending on Monday, when he publicly announced the relationship after weeks of rumors that the two were dating. In a post on Facebook, Woods wrote, "Lindsey and I have been friends for some time, but over the last few months we have become very close and are now dating. We thank you for your support and for respecting our privacy. We want to continue our relationship, privately, as an ordinary couple and continue to compete as athletes."

Woods’ roster of previous mistresses during his marriage to Elin Nordegren also included New York City club hostess Rachel Uchitel, “Tool Academy” reality contestant Jamie Grubbs, and several porn stars and alleged prostitutes.

James also claimed after the scandal broke that Woods had paid her and another partner $2,000 to participate in a threesome with him, the Huffington Post reported.

In a message on her Twitter account on Monday, Rachel Uchitel wrote,” “Everyone deserves a second chance. No exceptions to that rule, in my humble opinion.”