Angelina Jolie has become the face of new Louis Vuitton brand's 'Core Values' campaign.

The 35-year-old actress appears in a stunning new ad for the brand's campaign going completely natural with no make-up on, posing in her own clothes with her long dark hair au natural and wavy. She is seen sitting barefooted aboard a traditional wooden boat with her own old monogrammed Alto Louis Vuitton bag slung around her shoulders. The photoshoot took place in Cambodia's Siem Reap province by famed photographer Annie Leibovitz.

Cambodia is the country close to her heart as its where she adopted her first 9-years old son Maddox.

Vuitton's executive vice president, Pietro Beccari, tells Women's Wear Daily, People are not used to seeing Angelina in this situation. I like the fact that it's a real moment. This travel message we give through personal journeys is a fundamental one for the brand...This campaign is about a very special person and a very special journey.

U2 star Bono, Buzz Aldrin, Mikhail Gorbachev and Sir Sean Connery have all posed for thr 'Core Value' campaign, which highlights the brand's roots in luggage and travel goods. While, in the past Madonna, Jennifer Lopez and Scarlett Johansson have been previous faces of the brand.

Jolie donated a chunk of her pay cheque earned from the campaign to charity. Just last week her partner, Brad Pit, 47, donated $500,000 to a charity that is helping to rebuild his tornado ravaged home state of Missouri.